Article

Cluster-based characterization of multi-dimensional tropospheric ozone variability in coastal regions: an analysis of lidar measurements and model results

Öffentlich Deposited
https://scholar.colorado.edu/concern/articles/cf95jd43x
Abstract
  • Coastalregionsaresusceptibletomultiplecomplexdynamicandchemicalmechanismsandemission sources that lead to frequently observed large tropospheric ozone variations. These large ozone variations occur on a mesoscale and have proven to be arduous to simulate using chemical transport models (CTMs). We present a clustering analysis of multi-dimensional measurements from ozone lidar in conjunction with both an offline GEOS-Chem chemical-transport model (CTM) simulation and the online GEOS-Chem simulation GEOS-CF, to investigate the vertical and temporal variability of coastal ozone during three recent air quality campaigns: 2017 Ozone Water-Land Environmental Transition Study (OWLETS)-1, 2018 OWLETS-2, and 2018 Long Is- land Sound Tropospheric Ozone Study (LISTOS). We developed and tested a clustering method that resulted in five ozone profile curtain clusters. The established five clusters all varied significantly in ozone magnitude verti- cally and temporally, which allowed us to characterize the coastal ozone behavior. The lidar clusters provided a simplified way to evaluate the two CTMs for their performance of diverse coastal ozone cases. An overall evalu- ation of the models reveals good agreement (≈ 0.70) in the low-level altitude range (0 to 2000 m), with a low and unsystematic bias for GEOS-Chem and a high systemic positive bias for GEOS-CF. The mid-level (2000– 4000 m) performances show a high systematic negative bias for GEOS-Chem and an overall low unsystematic bias for GEOS-CF and a generally weak agreement to the lidar observations (0.12 and 0.22, respectively). Evaluating cluster-by-cluster model performance reveals additional model insight that is overlooked in the over- all model performance. Utilizing the full vertical and diurnal ozone distribution information specific to lidar measurements, this work provides new insights on model proficiency in complex coastal regions.

Creator
Date Issued
  • 2022
Academic Affiliation
Journal Title
Journal Issue/Number
  • 23
Journal Volume
  • 22
Zuletzt geändert
  • 2025-01-10
Resource Type
Urheberrechts-Erklärung
License
DOI
ISSN
  • 1680-7324
Language

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