Article

Thermo-responsive poly(N-isopropylacrylamide) (PNIPAM) hydrogel particles improve workability loss and autogenous shrinkage in cement paste

Pubblico Deposited
https://scholar.colorado.edu/concern/articles/cf95jd179
Abstract
  • In this work, we show that non-superabsorbent, thermo-responsive poly(N-isopropyl acrylamide) (PNIPAM) hydrogel particles (< 250 μm) can reduce autogenous shrinkage in cement paste and improve early-age stiffening that can be caused by traditional superabsorbent polymers (SAPs). Swelling measurements in DI water and cement filtrate solution suggest that SAP-induced early-age stiffening is caused by its super-absorbency in low-ionic solutions – a behavior not exhibited by non-superabsorbent PNIPAM. Addition of PNIPAM resulted in a 29% and 60% reduction in autogenous shrinkage strain at 14 days when used alone (0.3 wt% PNIPAM) and in combination with SAP (0.15% PNIPAM, 0.15% SAP), respectively, compared to a Control with no polymer addition. Furthermore, an addition of 0.3 wt.% PNIPAM exhibited a ∼29% and ∼37% decrease in static yield stress compared to a Control and 0.3 wt% SAP-modified cement pastes, respectively. Taken together, the results provide initial evidence to suggest that the use of hydrogels as internal curing agents may not necessarily require super-absorbency to reduce autogenous shrinkage. Non-superabsorbent hydrogels, like PNIPAM, may help reduce autogenous shrinkage while alleviating the effects of SAP-induced early-age stiffening.

     

Creator
Date Issued
  • 2022
Academic Affiliation
Journal Title
Journal Volume
  • 10
Ultima modifica
  • 2023-08-03
Resource Type
Dichiarazione dei diritti
License
DOI
ISSN
  • 2666-5492
Language

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