Undergraduate Honors Thesis
Self-Alignment of Gold Nanorods Within Cellulose Based Liquid Crystals Public Deposited
https://scholar.colorado.edu/concern/undergraduate_honors_theses/x346d467n
- Abstract
- In this work, I use cellulose nanocrystals and demonstrate the long-range bulk dispersion and self-alignment of anisotropic metal nanoparticles at well-de ned orientation with respect to the far- eld liquid crystal director. In the case of anisotropic plasmonic nanoparticles, the liquid crystal-mediated alignment and assembly result in a switchable polarization-sensitive plasmon resonance, di erent from that of the same nanoparticles in isotropic media. Polarization-sensitive absorption, scattering, and two-photon luminescence are used to characterize orientations and spatial distributions of nanorods. E ective-medium optical properties of these hybrid inorganic-organic plasmonic complex uids match what one could expect based on entropic interactions of gold nanorods with the structured host medium of the nanocrystal- based liquid crystal. The demonstrated device-scale bulk nanoparticle self-alignment and self-assembly may enable optical metamaterial mass production and new properties arising from combining the switchable nanostructured LCs and properties of anisotropic plasmonic nanoparticles.
- Creator
- Date Awarded
- 2012-11-02
- Academic Affiliation
- Advisor
- Granting Institution
- Subject
- Last Modified
- 2019-12-02
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Thumbnail | Title | Date Uploaded | Visibility | Actions |
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selfAlignmentOfGoldNanorodsWithinCelluloseBasedLiquidCry.pdf | 2019-11-19 | Public | Download |