Graduate Thesis Or Dissertation
Structure-Property Relationships in de Vries Smectic A Liquid Crystals Public Deposited
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Liquid crystals (LCs) have become inextricably linked with the display industry in recent years. As screen sizes increase the response time of the LC must decrease to maintain picture quality. A rare subset of the chiral smectic A (SmA*) , known as the de Vries SmA* phase, shows fast switching times, large electroclinic tilts, native gray-scale and small layer shrinkage when driven by an electric field, making it an attractive alternative to SmC* materials for next-generation displays. The de Vries SmA* phase is typically formed by molecules with one or more tails that strongly suppress out-of-layer fluctuations.
The first part of this thesis describes a set of mesogens with four different liquid crystalline cores built on a scaffold possessing a phenyl and biphenyl moiety linked by an ester with two peripheral alkoxy side-chains (tails). One side-chain is the (S)-1-methylheptyloxy group ortho to a trifluoromethyl group. The second side chain is varied between an n-alkoxy-, n-alkenyloxy- and semifluorinated tails, all of the same length. The latter two tails have been shown to suppress out-of-layer fluctuations. Only the LCs built on the hydroquinone stereopolar unit (W652/W657/W530) show the desired liquid crystalline phases (SmA* and SmC*) over a convenient temperature range. Surprisingly, W652, which possesses no strong out-of-layer suppressing group, shows the de Vries SmA* phase, suggesting the core may be as important as the tails in the design of de Vries smecticss.
The second part of this thesis develops structure-property relationships of compounds built on the hydroquinone stereopolar unit, which is particularly good at promoting the de Vries SmA* phase. The set of lateral polar groups (H, Me, Cl, CF3 or NO2) and achiral tails were varied. The effect on the width of the SmA* phases, the clearing point, saturated electroclinic tilt, layer shrinkage from SmA* to SmC* and spontaneous polarization in the SmC* phase were examined. Materials with a large electronegative lateral polar group and strongly out-of-layer suppressing tails give the most desirable properties.
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- 2015
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- 2020-01-30
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structurePropertyRelationshipsInDeVriesSmecticALiquidCry.pdf | 2019-11-13 | Public | Download |