Article

Abstract

• Oligodeoxyribonucleotides bearing boranephosphonate linkages (bpDNA) were shown to reduce a number of metal ions and form nanoparticles through a novel reaction pathway that leads to phosphate diesters or phosphate triesters in water or alcohols respectively. The synthetic utility of this reaction was further demonstrated through the synthesis of oligodeoxyribonucleotides containing phosphate triester linkages. This new reactivity also makes bpDNA promising for use in construction of DNA templated metallic nanostructures.

Creator

• Padar, Petra
• Roy, Subhadeeo
• McCuen, Heather Brummel
• Caruthers, Marvin H.
• Olesiak, Magdalena

Date Issued

• 2012-09-26

Academic Affiliation

• Chemical and Biological Engineering

Journal Title

• Organic and Biomolecular Chemistry

Journal Issue/Number

• 46

Journal Volume

• 10

File Extent

• 9130-9133

Last Modified

• 2019-12-05

Resource Type

• Article

Rights Statement

• In Copyright

DOI

• 10.1039/C2OB26661J

ISSN

• 1477-0520

Language

• English [eng]

Relationships

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